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Photostability of the Oleic Acid-Encapsulated Water-Soluble CdxSeyZn1-xS1-y Gradient Core-Shell Quantum Dots

机译:油酸包封的水溶性CdxseyZn1-xs1-y梯度核壳量子点的光稳定性

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摘要

Composite systems where quantum dots (QDs) are combined with other nanomaterials (e.g., gold nanorods) in aqueous solutions have attracted broad attention - both for their potential in applications and for studies of fundamental processes. However, high-quality QDs are typically prepared in organic solvents, and the transfer of QDs to an aqueous phase is needed to create the desired QD composites. Photostability of the transferred QDs - both the steady-state and photo-induced dynamic properties - is essential for studying the processes in the composites and for their applications. We present a detailed study of the photostability of aqueous CdxSeyZn1-xS1-y gradient core-shell QDs obtained by various approaches using linker exchange and surfactant encapsulation. Beside the steady-state photoluminescence (PL) emission stability, we also study changes in the PL decay. From the variety of the studied samples, the water-soluble QDs encapsulated by a double layer of oleic acid show superior properties, that is, stable PL emission and PL decay under continuous light or pulsed-laser light irradiation. We demonstrate that the double-layer encapsulation of QDs can be used to create QDs-metal nanoparticle composites.
机译:在水溶液中将量子点(QD)与其他纳米材料(例如金纳米棒)结合的复合系统已引起广泛关注-既有其在应用中的潜力,也有对其基础工艺的研究。然而,通常在有机溶剂中制备高质量的QD,并且需要将QD转移到水相中才能生成所需的QD复合材料。转移的量子点的光稳定性-稳态和光诱导的动态特性-对于研究复合材料的工艺及其应用至关重要。我们目前通过使用接头交换和表面活性剂封装的各种方法获得的CdxSeyZn1-xS1-y梯度核-壳QD水溶液的光稳定性的详细研究。除了稳态光致发光(PL)发射稳定性外,我们还研究了PL衰减的变化。从各种研究样品中,被双层油酸包封的水溶性量子点表现出优异的性能,即在连续光或脉冲激光照射下稳定的PL发射和PL衰减。我们证明了QDs的双层封装可用于创建QDs-金属纳米颗粒复合材料。

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